Polyamorphism in Yb-based metallic glass induced by pressure

نویسندگان

  • Liangliang Li
  • Qiang Luo
  • Renfeng Li
  • Haiyan Zhao
  • Karena W. Chapman
  • Peter J. Chupas
  • Luhong Wang
  • Haozhe Liu
چکیده

The Yb62.5Zn15Mg17.5Cu5 metallic glass is investigated using synchrotron x-ray total scattering method up to 38.4 GPa. The polyamorphic transformation from low density to high density with a transition region between 14.1 and 25.2 GPa is observed, accompanying with a volume collapse reflected by a discontinuousness of isothermal bulk modulus. This collapse is caused by that distortional icosahedron short range order precedes to perfect icosahedron, which might link to Yb 4f electron delocalization upon compression, and match the result of in situ electrical resistance measurement under high pressure conditions. This discovery in Yb-based metallic glass, combined with the previous reports on other metallic glass systems, demonstrates that pressure induced polyamorphism is the general behavior for typical lanthanide based metallic glasses.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Simulation of pressure-induced polyamorphism in a chalcogenide glass GeSe2

The pressure-induced insulator-metal transition in amorphous GeSe2 (a-GeSe2) is studied using an ab initio constant pressure molecular-dynamic simulation. a-GeSe2 transforms gradually to an amorphous metallic state under the application of pressure. The transition is reversible, and is associated with a gradual change from fourfold to sixfold Ge coordination, and from twofold to fourfold Se coo...

متن کامل

Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System

We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies a...

متن کامل

Ultrahigh-pressure polyamorphism in GeO2 glass with coordination number >6.

Knowledge of pressure-induced structural changes in glasses is important in various scientific fields as well as in engineering and industry. However, polyamorphism in glasses under high pressure remains poorly understood because of experimental challenges. Here we report new experimental findings of ultrahigh-pressure polyamorphism in GeO2 glass, investigated using a newly developed double-sta...

متن کامل

Pressure effects on Ca60Al40 metallic glass superconductors

Theoretical computation of the pressure dependence superconducting state parameters of binary Ca60Al40 is reported using model potential formalism. Explicit expressions have been derived for the volume dependence of the electron–phonon coupling strength λ and the Coulomb pseudopotential μ* considering the variation of Fermi momentum KF and Debye temperature ӨD with volume. Well known Ashcroft’s...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 7  شماره 

صفحات  -

تاریخ انتشار 2017